Prioritize scaling by safely stacking (Q) and using (W) to negate Sion's poke and engage attempts.
Maintain medium lane pressure to avoid giving Sion a passive lane and prevent him from safely stacking health with (W).
This is a control vs teamfight scaling matchup where Gwen must survive early pressure and outscale Sion's frontline durability.
Trading pattern
Engage in extended trades only when (Q) is fully stacked and (W) is ready to block Sion's retaliations.
Punish Sion after he wastes (Q) charge or when his (W) shield is down by stepping forward with (E) and (Q) damage.
Use (R) after setting up with (Q) stacks to slow and chase, forcing Sion to respect your damage and limiting his engage angles.
Danger windows
Be cautious when Sion has (Q) charged from fog or brush angles, as it can knock you up and disrupt your trades.
Avoid fighting when (R) is off cooldown and he has a clear path to engage, sidestepping or breaking his angle.
Do not commit to trades when your (W) is down, as you become vulnerable to Sion's poke and burst trades.
Early game
Focus on farming and stacking (Q) before committing to trades to avoid Sion's early poke and charged (Q) knockup.
Use (E) to control spacing and dodge (Q) charge or (E) slow setups.
Avoid extended trades before level 6 when Gwen's all-in threat with (R) is unavailable.
Power spikes
At level 6, use (R) to enhance chase and slow, turning extended trades into kills if (Q) is stacked and (W) is available.
After your first two AP items, pressure side lanes and teamfights where (W) can deny Sion's outside damage and you can outduel him.
Respect Sion's level 6 (R) engage and his high health scaling with (W) shield, avoiding fights when his shield is up and (R) is ready.
Win conditions
Reach your AP item spikes and stack (Q) before committing to extended fights where (W) can block Sion's retaliation.
Use (E) and (W) to control spacing and negate Sion's engage tools, forcing him into short trades you can outlast.
Pressure side lanes and join teamfights where your (W) protects you from outside damage, allowing you to output sustained DPS against Sion's frontline.
Tip: For Gwen vs Sion, read overview, trading pattern, and danger windows first for a fast Top lane check.